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The following molecule contains an _____________functional group. The following molecule contains an _____________functional group.

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Which of the following is a tertiary amine?


A) CH3CH2N(CH3) 2
B) (CH3) 3CNH2
C) CH3CH2NHCH3
D) CH3CH2NHCH(CH3) 2

E) A) and B)
F) C) and D)

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Which of the following best represents the shape of the 2s atomic orbital of carbon? Which of the following best represents the shape of the 2s atomic orbital of carbon?   A) 1 B) 2 C) 3 D) 4


A) 1
B) 2
C) 3
D) 4

E) B) and D)
F) A) and D)

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How many electrons are there in the valence shell of the carbon atom of the methyl anion, CH3-?


A) 2
B) 4
C) 6
D) 8

E) C) and D)
F) A) and D)

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Which atomic orbitals overlap to form the C-O bond of dimethyl ether, (CH3) 2O?


A) C 2sp3 + O 2sp2
B) C 2sp2 + O 2p
C) C 2sp2 + O 2sp2
D) C 2sp3 + O 2sp3

E) B) and D)
F) B) and C)

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Which of the following best represents an sp2 hybridized atomic orbital of carbon which overlaps with the 1s atomic orbital of hydrogen to form a C-H σ\sigma bonding molecular orbital in ethene, H2C=CH2  Which of the following best represents an sp<sup>2</sup> hybridized atomic orbital of carbon which overlaps with the 1s atomic orbital of hydrogen to form a C-H  \sigma bonding molecular orbital in ethene, H<sub>2</sub>C=CH<sub>2</sub>   A) 1 B) 2 C) 3 D) 4


A) 1
B) 2
C) 3
D) 4

E) C) and D)
F) None of the above

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Provide a neatly drawn figure to show the atomic orbitals that overlap to form each of the bonds in ammonia (NH3) and which contain the lone pair of electrons. Label each orbital with its hybridization.

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What is the approximate value of the H-C-H bond angles in a methyl anion, CH3-?


A) 90 \circ
B) 109 \circ
C) 120 \circ
D) 180 \circ

E) A) and D)
F) A) and C)

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How many electrons are there in the valence shell of the nitrogen atom of ammonia?


A) 4
B) 5
C) 6
D) 8

E) A) and B)
F) None of the above

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The following species forms during an organic reaction. The following species forms during an organic reaction.   The formal charge on the carbon atom indicated by the arrow is +1. The formal charge on the carbon atom indicated by the arrow is +1.

A) True
B) False

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How many electrons can the shell with a principal quantum number of 1 hold?


A) 1
B) 2
C) 4
D) 8

E) All of the above
F) A) and B)

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Which of the following resonance structures is the least important contributor to the resonance hybrid of the acetate anion, CH3COO-? Which of the following resonance structures is the least important contributor to the resonance hybrid of the acetate anion, CH<sub>3</sub>COO<sup>-</sup>?   A) 1 B) 2 C) 3 D) 4


A) 1
B) 2
C) 3
D) 4

E) All of the above
F) A) and B)

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How many electrons can the shell with a principal quantum number of 2 hold?


A) 1
B) 2
C) 4
D) 8

E) B) and C)
F) None of the above

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Which of the following compounds is an aldehyde?


A) CH3CH2CH2COOH
B) CH3CH2CHO
C) CH3CH2CH2OH
D) CH3CH2COCH3

E) None of the above
F) All of the above

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Which of the following species possesses a formal charge?


A) BH3
B) BH4
C) CCl4
D) H2S

E) C) and D)
F) A) and C)

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Which of the following bonds has the smallest dipole moment?


A) Li-Cl
B) C-H
C) O-H
D) H-Cl

E) A) and B)
F) A) and C)

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The following molecule is classified as a __________amine. The following molecule is classified as a __________amine.

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The formal charge on carbon in carbon monoxide is______.

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Which of the following molecules is not linear?


A) H2O
B) CO2
C) HC \equiv CH
D) Cl2

E) B) and D)
F) C) and D)

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Which of the following is/are tetrahedral? 1) methane, CH4 2) methyl carbocation, CH3+ 3) methyl carbanion, CH3- 4) methyl radical, CH3-


A) only 1 and 2
B) only 1 and 3
C) only 1 and 4
D) only 2 and 3

E) B) and C)
F) C) and D)

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